Claisen condensation is similar to aldol condensation, but is involves two esters instead of two aldehydes. MathJax reference. Product of an intramolecular aldol condensation, Product of intramolecular aldol condensation of 3-methyloctane-2,7-dione, Deciding which α-Η gets abstracted in aldol condensation, Selectivity in aldol condensation of 7-oxo(6,6-²H₂)octanal, Major product for aldol condensation between acetophenone and acetaldehyde. Looks like you’ve clipped this slide to already. Asking for help, clarification, or responding to other answers. This enolate anion is relatively stable due to the delocalization of the negative charge (electrons). Moving to the aldol condensation I can't figure out which product will be the main. In fact if you somehow make product B via a different route and then treat it with ethoxide, you should exclusively get product A out of your flask, via retro-Claisen and Claisen condensation. This enolate ion is stabilized by the delocalization of electrons. My approach was that the base will deprotonate the substrate in order to produce the most stable enolate. Your email address will not be published. An illustration of this reaction is provided below. A carbonyl compound that contains an α hydrogen is in equilibrium with its own enol. How to manage a remote team member who appears to not be working their full hours? Making statements based on opinion; back them up with references or personal experience. Use MathJax to format equations. Chemistry Stack Exchange is a question and answer site for scientists, academics, teachers, and students in the field of chemistry. This leads to the formation of a beta-diketone or a beta-keto ester, which is immediately isolated. The one produced in A has one alkyl group while the B has two. Would the Millennium Falcon have been carried along on the hyperspace jump if it stayed attached to the Star Destroyer? 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